Tag: M.W=100-150

Chen, Jianzhong; Zhang, Zhenfeng; Li, Bowen; Li, Feilong; Wang, Yulin; Zhao, Min; Gridnev, Ilya D.; Imamoto, Tsuneo; Zhang, Wanbin published the artcile< Pd(OAc)2-catalyzed asymmetric hydrogenation of sterically hindered N-tosylimines>, Recommanded Product: 2,2,5,5-Tetramethyldihydrofuran-3(2H)-one, the main research area is tosylamine preparation enantioselective; tosylimine preparation hydrogenation palladium catalyst.

An efficient palladium acetate (an inexpensive Pd salt with low toxicity) catalyzed asym. hydrogenation of sterically hindered N-tosylimines RC(R1)=NS(O)2R2 (R = t-Bu, 1-methoxycyclohexyl, adamantan-1-yl, etc.; R1 = Ph, 2H-1,3-benzodioxol-5-yl, Me, etc.; R2 = Ph, Me, 4-FC6H4, etc.), (E)-N-(2,2-Dimethylcyclopentylidene)-4-methylbenzenesulfonamide and (E)-4-Methyl-N-(2,2,5,5-tetramethyldihydrofuran-3(2H)-ylidene)benzenesulfonamide is realized with high catalytic activities (S/C up to 5000) and excellent enantioselectivities (ee up to 99.9%). Quantum chem. calculations suggest that uniformly high enantioselectivities are observed due to the structurally different S- and R-reaction pathways.

Nature Communications published new progress about Amines, chiral Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (tosyl). 5455-94-7 belongs to class tetrahydrofurans, and the molecular formula is C8H14O2, Recommanded Product: 2,2,5,5-Tetramethyldihydrofuran-3(2H)-one.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Anteunis, M.; Vandewalle, M. published the artcile< Long-range phenomena. XII. Organic mass spectrometry. VII. Enolization in 3-oxotetrahydrofuran. PMR and MS study>, Electric Literature of 5455-94-7, the main research area is PMR oxotetrahydrofuran enolization; mass spectra oxotetrahydrofuran enolization.

A PMR study shows extensive enolization in the 3-oxotetrahydrofurans with branched substitution at C-5. Next to classical M-mode long range couplings, non-planar (non-classical) long range couplings, J(2,4) and J(2,5) are common features. The 3-oxotetrahydrofuran ring is easily changed conformationally, which is reflected by changes in vicinal and long range coupling values. The mass spectra of the keto- and enol mols. show different fragmentation patterns. The expulsion of an alkane moiety, directly from the molecular ion (M+), is observed for the enol form. Mass spectrometry allows easy characterization of C-2 or C-5-substituted 3-oxotetrahydrofurans.

Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy published new progress about Mass spectra. 5455-94-7 belongs to class tetrahydrofurans, and the molecular formula is C8H14O2, Electric Literature of 5455-94-7.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Kuang, Bifeng; Zhang, Qian; Fang, Yanxiong; Bai, Yong; Qiu, Songbai; Wu, Ping; Qin, Yanlin; Wang, Tiejun published the artcile< Ring Opening of Cyclic Ether for Selective Synthesis of Renewable 1,5-Pentanediol over Pt/WO3@SiO2 Catalysts>, HPLC of Formula: 97-99-4, the main research area is ring opening catalyst cyclic ether renewable pentanediol.

In this paper, the WO3-embedded in mesoporous SiO2 framework (WO3@SiO2) was developed using facile modified sol-gel, and was further applied as the support of Pt/WO3@SiO2 catalysts during impregnation. The ring-opening of cyclic ether such as biomass-derived tetrahydrofurfuryl alc. (THFA), for selective synthesis of renewable 1, 5-pentanediol (1, 5-PeD), was efficiently accomplished over Pt/WO3@SiO2 catalysts. This special nanocomposite structure provided both abundant active sites and strong synergetic coupling, thus significantly boosting the catalytic performances. The effects of reaction parameters were also investigated on the catalytic performances, including W/Si molar ratio, reaction time, reaction temperature and reduction temperature The high THFA conversion of 82.9% and 1, 5-PeD selectivity of 72.9% were achieved under the optimized reaction conditions. The preliminary characterization results suggested that the Bronsted acid sites of HxWO3 species with proper acid amounts played an important role in controlling the selective ring-opening of THFA cyclic ether towards 1, 5-PeD.

Industrial & Engineering Chemistry Research published new progress about Biomass. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, HPLC of Formula: 97-99-4.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Rhee, Sung W.; DeGraw, Joseph I.; Kaegi, Heinz H. published the artcile< Synthesis of a new class of retinoid, tritium-labeled TTNPB [(E)-4-[2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)-1-propenyl]benzoic acid] with a high specific activity>, SDS of cas: 5455-94-7, the main research area is retinoidal benzoic acid tritium labeled; naphthalenylpropenylbenzoic acid retinoid tritium labeled.

The labeled retinoidal benzoic acid I was prepared starting with C6H6 and furanone II via catalytic tritiation of dihydronaphthalene III.

Journal of Labelled Compounds and Radiopharmaceuticals published new progress about 5455-94-7. 5455-94-7 belongs to class tetrahydrofurans, and the molecular formula is C8H14O2, SDS of cas: 5455-94-7.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Gao, Rui; Li, Xiang; Guo, Lingyun; Tong, Zhikun; Deng, Qiang; Wang, Jun; Zeng, Zheling; Zou, Ji-Jun; Deng, Shuguang published the artcile< Pyrochlore/Al2O3 composites supported Pd for the selective synthesis of cyclopentanones from biobased furfurals>, Application of C5H10O2, the main research area is pyrochlore alumina supported palladium catalyst cyclopentanones biobased furfural.

Designing a bifunctional catalyst with both highly selective C=O hydrogenation ability and Lewis acid-catalyzed ring-rearrangement ability is highly important for the synthesis of the cyclopentanone motifs from furfural derivatives Herein, a class of pyrochlore/Al2O3 composites (2.68 wt%Y2(Sn0.65Al0.35)2O7-δ/Al2O3, 7.74 wt%Y2(Sn0.65Al0.35)2O7-δ/Al2O3) with a onefold Lewis acidity and rich oxygen defects were synthesized via a dissolution-precipitation method. After the impregnation by Pd nanoparticles, the oxygen defect of pyrochlore/Al2O3 shows a bifunctional effect: they can adsorb C=O, promoting the selective C=O hydrogenation step and can enhance the accessibility of coordinatively unsaturated metal ions, providing Lewis acidic sites for the ring-rearrangement step. The composite-based catalysts show noticeably higher hydrogenation and hydrolysis rates than their corresponding single metal oxide-based catalysts (Pd/Al2O3, Pd/Y2Sn2O7). Finally, 7.74 wt%Y2(Sn0.65Al0.35)2O7-δ/Al2O3 shows a cyclopentanone yield of 98.1% and a 3-hydroxymethyl cyclopentanone yield of 90.6%. ATR-IR results verify the catalytic mechanism and emphasize the importance of oxygen defects.

Applied Catalysis, A: General published new progress about Acidity. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Application of C5H10O2.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Ruan, Luna; Pei, An; Liao, Jianhua; Zeng, Li; Guo, Guangrong; Yang, Kai; Zhou, Qin; Zhao, Ning; Zhu, Lihua; Chen, Bing Hui published the artcile< Nitrogen-doped carbon nanotubes-supported PdNiCo nanoparticles as a highly efficient catalyst for selective hydrogenation of furfural>, Synthetic Route of 97-99-4, the main research area is furfural selective hydrogenation catalyst.

Nitrogen-doped carbon nanotubes (N-CNTs) was synthesized via covalent functionalization, and the monometallic (Pd/CNTs, Pd/N-CNTs), bimetallic (NiCo/CNTs, NiCo/N-CNTs, PdNi/CNTs, PdCo/CNTs, PdNi/N-CNTs, PdCo/N-CNTs) and trimetallic (PdNiCo/CNTs, PdNiCo/N-CNTs) catalysts were prepared by simple liquid chem. reduction The catalytic performance of as-obtained catalysts was evaluated by furfural hydrogenation. The properties of electron and surface active sites and nanostructures of as-prepared catalysts were characterized. And the relationship between the above-mentioned characteristic textures and catalytic performance of as-synthesized catalysts was further discussed and established. 97.1% Selectivity to tetrahydrofurfuryl alc. could be obtained over PdNiCo/N-CNTs (furfural conversion-100%), but tetrahydrofurfuryl alc. selectivity was only 41.8% when using PdNiCo/CNTs. This investigation confirmed that the catalytic performance of PdNiCo/N-CNTs was much more excellent than other catalysts mainly due to its own PdNiCo alloy nanostructure and the electronic synergy effect between PdNiCo metallic nanoparticles and N-CNTs. Furthermore, there were much weaker basic sites in PdNiCo/N-CNTs, which greatly increased its catalytic properties.

Fuel published new progress about Hydrogenation. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Synthetic Route of 97-99-4.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Bakharev, Vladimir V.; Gidaspov, Alexander A.; Zalomlenkov, Vladimir A.; Parfenov, Victor E.; Golovina, Olga V.; Slepukhin, Pavel A. published the artcile< Opening of the 1,3,5-triazine ring in 3-methyl-5-(trinitromethyl)tetrazolo[1,5-a][1,3,5]triazin-7-one by the action of alcohols>, Product Details of C5H10O2, the main research area is tetrazolotriazinone ring opening alc.

It was shown for the first time that in the reaction of 3-methyl-5-(trinitromethyl)tetrazolo[1,5-a][1,3,5]triazin-7-one with alcs. in the presence of bases, along with the expected substitution of the trinitromethyl group, opening of the 1,3,5-triazine ring with the addition of an alc. at the site of the C-N bond cleavage takes place. It was found that in the absence of bases only opening of the 1,3,5-triazine ring occurs with the formation of alkyl esters of {1-[(1-methyl-1H-tetrazol-5-yl)imino]-2,2,2-trinitroethyl}carbamic acid, and the trinitromethyl group retains high reactivity and can be substituted by the action of alcs. in the presence of a base.

Chemistry of Heterocyclic Compounds (New York, NY, United States) published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Product Details of C5H10O2.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Fovanna, Thibault; Campisi, Sebastiano; Villa, Alberto; Kambolis, Anastasios; Peng, Gael; Rentsch, Daniel; Krocher, Oliver; Nachtegaal, Maarten; Ferri, Davide published the artcile< Ruthenium on phosphorous-modified alumina as an effective and stable catalyst for catalytic transfer hydrogenation of furfural>, Electric Literature of 97-99-4, the main research area is ruthenium phosphorus modified alumina catalyst preparation furfural hydrogenation.

Supported ruthenium was used in the liquid phase catalytic transfer hydrogenation of furfural. To improve the stability of Ru against leaching, phosphorus was introduced on a Ru/Al2O3 based catalyst upon impregnation with ammonium hypophosphite followed by either reduction or calcination to study the effect of phosphorus on the physico-chem. properties of the active phase. Characterization using X-ray diffraction, solid state 31P NMR spectroscopy, X-ray absorption spectroscopy, temperature programmed reduction with H2, IR spectroscopy of pyridine adsorption from the liquid phase and transmission electron microscopy indicated that phosphorus induces a high dispersion of Ru, promotes Ru reducibility and is responsible for the formation of acid species of bronsted character. As a result, the phosphorus-based catalyst obtained after reduction was more active for catalytic transfer hydrogenation of furfural and more stable against Ru leaching under these conditions than a benchmark Ru catalyst supported on activated carbon.

RSC Advances published new progress about Calcination. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Electric Literature of 97-99-4.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Netto-Ferreira, J. C.; Wintgens, V.; Scaiano, J. C. published the artcile< Lifetimes of biradicals produced in the Norrish Type I reaction of methyl-substituted 2-tetralones>, Application of C8H14O2, the main research area is Norrish photolysis biradical lifetime tetralone.

The Norrish Type I biradicals derived from 2-tetralones decay by a competition of recyclization to the starting material, intramol. disproportionation to yield aldehydes and decarbonylation. The last path is only favored in the case of 3,3-dimethylated derivatives while, in the other extreme, the parent 2-tetralone is essentially photostable. The biradical lifetimes are around 140 ns in benzene and 40 ns or less in nonaromatic solvents; they show little sensitivity to the solvent polarity and hydrogen bonding ability. The remarkable stabilization of the biradical in benzene is probably due to specific interactions between the acyl center in the biradical and benzene, since similar effects have not been observed in other biradicals.

Journal of Photochemistry and Photobiology, A: Chemistry published new progress about Biradicals Role: RCT (Reactant), RACT (Reactant or Reagent). 5455-94-7 belongs to class tetrahydrofurans, and the molecular formula is C8H14O2, Application of C8H14O2.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Tang, Feiying; Wang, Liqiang; Dessie Walle, Maru; Mustapha, Abdulhadi; Liu, You-Nian published the artcile< An alloy chemistry strategy to tailoring the d-band center of Ni by Cu for efficient and selective catalytic hydrogenation of furfural>, Category: tetrahydrofurans, the main research area is nickel copper alloy catalyst furfural hydrogenation morphol textural property.

Nickel is a promising catalyst for the hydrogenation of furfural (FA) into furfuryl alc. (FOL) and tetrahydrofurfuryl alc. (TFOL). However, slow H* desorption and low catalytic selectivity limit its practical application. Herein, we employed an alloying strategy to tailoring the d-band center of Ni by Cu for efficient and selective catalytic hydrogenation of furfural. A series of Ni-Cu alloy catalysts (NiCux/C) were prepared by pyrolyzing NiCux-BTC (a MOF containing Cu and Ni) precursors. Theor. calculation demonstrates that Ni exhibits a downshifted d-band center once alloyed by Cu. This change can not only promote the desorption of H from Ni surface to improve the catalytic activity but also thermodynamically favor the transformation of adsorption orientation of FA (from a flat orientation on Ni to a tilted one on Ni-Cu alloy) to enable the selective conversion of FA into FOL or TFOL on demand. NiCu0.33/C catalyst exhibits enhanced activity and selectivity for FA hydrogenation compared to pure Ni and Cu.

Journal of Catalysis published new progress about Density of states. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Category: tetrahydrofurans.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem