Category: 4415-87-6

Ishii, Hidenori; Tetsutani, Hisashi; Nagi, Tatsuya published the artcile< Improving liquid crystal alignment ability and UV sensitivity in photodecomposition polyimide film>, SDS of cas: 4415-87-6, the main research area is carboxylic dianhydride liquid crystal UV sensitivity photodecomposition.

A liquid crystal alignment film with fewer processes capable of imparting anisotropy was developed using a polyimide, which utilized the cleavage of a cyclobutane ring by irradiation of polarized UV light at 254 nm. When an aromatic diamine with alkylene in the mol. center was used, an even methylene number of diamines showed superior liquid crystal alignment ability compared with diamines with an odd methylene number Addnl., a diamine containing a mol. structure with a pre-imidized imide group adjoined to a cyclobutane ring was extremely effective in improving liquid crystal alignment ability and sensitivity to polarized UV light.

Journal of Photopolymer Science and Technologypublished new progress about Anisotropy. 4415-87-6 belongs to class tetrahydrofurans, and the molecular formula is C8H4O6, SDS of cas: 4415-87-6.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Sornkamnerd, Saranyoo; Sasaki, Shuhei; Mitsumata, Tetsu; Takada, Kenji; Okada, Tomohiro; Ando, Shinji; Kaneko, Tatsuo published the artcile< Orientation Analysis of Polymer Chains in Optically Transparent Biopolyimides Having Rigid and Bending Backbones>, Quality Control of 4415-87-6, the main research area is optically transparent biopolyimide polymer chain orientation.

Optically transparent and heat-resistant polymer films are useful in the field of organic glasses usable for elec. insulators for panels, windows, optical devices, etc. A series of biopolyimides having non-π-conjugated backbones prepared using a renewable diamine, 4,4′-diaminotruxillic acid di-Me esters, and various dianhydride monomers were prepared and cast onto substrates to form transparent films with high heat resistances and good elec. resistance. The second order orientation coefficients (P200) of the biopolyimide films were evaluated by polarized attenuated total reflection Fourier-transform IR spectroscopy, and the P200 values for the C-N stretching vibrations at a wavenumber of 1365 cm-1 displayed a good correlation with that for the aromatic C-C stretching at 1510 cm-1, regardless of the dianhydride structure. The in-plane/out-of-plane birefringence and coefficients of linear thermal expansion exhibited strong correlations with P200 except for those of a few samples. Most of the biopolyimide films exhibited good transparencies with low birefringence and high elec. resistance, which are applicable to flexible substrates with a low coefficient of thermal expansion for panel displays.

ChemistrySelectpublished new progress about Birefringence. 4415-87-6 belongs to class tetrahydrofurans, and the molecular formula is C8H4O6, Quality Control of 4415-87-6.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Dwivedi, Sumant; Nag, Aniruddha; Sakamoto, Shigeki; Funahashi, Yasuyoshi; Harimoto, Toyohiro; Takada, Kenji; Kaneko, Tatsuo published the artcile< High-temperature resistant water-soluble polymers derived from exotic amino acids>, HPLC of Formula: 4415-87-6, the main research area is temperature resistant water soluble polyimide preparation.

High-performance water-soluble polymers have a wide range of applications from engineering materials to biomedical plastics. However, existing materials are either natural polymers that lack high thermostability or rigid synthetic polymers. Therefore, we design an amino acid-derived building block, 4,4′-diamino-α-truxillate dianion (4ATA2-), that induces water solubility in high-performance polymers. Polyimides containing 4ATA2- units are intrinsically water-soluble and are processed into films cast from an aqueous solution The resulting polyimide films exhibit exceptional transparency and extremely high thermal stability. In addition, the films can be made insoluble in water by simple post-treatment using weak acid or multivalent metal ions such as calcium. The synthesized polyimide’s derived from bio-based resources are useful for yielding waterborne polymeric high-performance applications.

RSC Advancespublished new progress about Elongation at break. 4415-87-6 belongs to class tetrahydrofurans, and the molecular formula is C8H4O6, HPLC of Formula: 4415-87-6.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Zhang, Qingfei; Kuang, Gaizhen; Zhou, Dongfang; Qi, Yanxin; Wang, Mingzhe; Li, Xiaoyuan; Huang, Yubin published the artcile< Photoactivated polyprodrug nanoparticles for effective light-controlled Pt(IV) and siRNA codelivery to achieve synergistic cancer therapy>, COA of Formula: C8H4O6, the main research area is photoactivated platinum polyprodrug nanoparticle Bcl2 siRNA synergy cancer therapy.

Endo/lysosomal escape and the subsequent controllable/precise release of drugs and genes are key challenges for efficient synergistic cancer therapy. Herein, we report a photoactivated polyprodrug nanoparticle system (PPNPsiRNA) centered on effective light-controlled codelivery of Pt(IV) prodrug and siRNA for synergistic cancer therapy. Under green-light irradiation, PPNPsiRNA can sustainedly generate oxygen-independent azidyl radicals to facilitate endo/lysosomal escape through the photochem. internalization (PCI) mechanism. Besides, concurrent Pt(II) release and siRNA unpacking could occur in a controllable manner after the decomposition of Pt(IV), main chain shattering of photoactivated polyprodrug and the PPNPsiRNA disassocn. Based on these innovative features, excellent synergistic therapeutic efficacy of chemo- and RNAi therapies of PPNPsiBcl-2 could be achieved on ovarian cancer cells under light irradiation The facile synthesized and prepared photoactivatable polyprodrug nanoparticle system provides a new strategy for effective gene/drug codelivery, where controllable endo/lysosomal escape and the subsequent drug/gene release/unpacking play vital roles, which could be adopted as a versatile codelivery nanoplatform for the treatment of various cancers.

Journal of Materials Chemistry B: Materials for Biology and Medicinepublished new progress about Antitumor agents. 4415-87-6 belongs to class tetrahydrofurans, and the molecular formula is C8H4O6, COA of Formula: C8H4O6.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Li, Pengfei; Lan, Hongling; Chen, Kuo; Ma, Xiupeng; Wei, Bingxin; Wang, Ming; Li, Peng; Hou, Yingfei; Jason Niu, Q. published the artcile< Novel high-flux positively charged aliphatic polyamide nanofiltration membrane for selective removal of heavy metals>, Recommanded Product: Cyclobuta[1,2-c:3,4-c’]difuran-1,3,4,6(3aH,3bH,6aH,6bH)-tetraone, the main research area is aliphatic polyamide nanofiltration membrane heavy metal removal separation.

The toxic heavy metals produced by the discharge of industrial wastewater pose a serious threat to the ecol. environment and human health. Nanofiltration (NF) membrane separation technol. is widely used in fields such as water softening, heavy metal removal and dye separation due to its environmental friendliness and low cost. Herein, a novel pos. charged aliphatic polyamide NF membrane (PEI-BTC) has been developed by using 1,2,3,4-cyclobutane tetracarboxylic acid chloride (BTC) monomer bearing a stereoscopic structure which undergoes classic interfacial polymerization (IP) with polyethyleneimine (PEI) on the Polyether sulfone (PES) support membrane. The physicochem. properties revealed that the PEI-BTC membrane had a larger mean effective pore size (0.285 nm), a thinner separation layer (40 nm) and a stronger pos. charged membrane surface (IEP = 7.25) than the traditional PEI-TMC membrane. Compared with previously reported PEI-based and com. NF membranes, the optimized PEI-BTC membrane exhibits a higher MgCl2 (2000 ppm) rejection of 97.53% and pure water flux of 156.85 kg·m-2·h-1 at 1.0 MPa. Moreover, the prepared PEI-BTC NF membrane shows excellent toxic heavy metal (1000 ppm) removal efficiency in the order of Mn (98.78%) > Zn (98.32%) > Ni (97.74%) > Cu (95.67%) > Cd (90.49%). The results demonstrate that the prepared pos. charged aliphatic polyamide NF membrane (PEI-BTC) has a unique industrial production potential for water softening and heavy metal removal.

Separation and Purification Technologypublished new progress about Contact angle. 4415-87-6 belongs to class tetrahydrofurans, and the molecular formula is C8H4O6, Recommanded Product: Cyclobuta[1,2-c:3,4-c’]difuran-1,3,4,6(3aH,3bH,6aH,6bH)-tetraone.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Yuan, Bingbing; Li, Pengfei; Wang, Peng; Yang, Hao; Sun, Honghong; Li, Peng; Sun, Haixiang; Niu, Q. Jason published the artcile< Novel aliphatic polyamide membrane with high mono-/divalent ion selectivity, excellent Ca2+, Mg2+ rejection, and improved antifouling properties>, Synthetic Route of 4415-87-6, the main research area is aliphatic polyamide nanofiltration membrane preparation water desalination ion rejection.

Monomer design and reconstruction is typically a preferred route to tune the inner structure and screen the performance of polyamide nanofilms for their efficiency and ease of scaling up in industrial production Herein, two kinds of novel acyl chloride monomers, 1,2,3,4-cyclobutane tetracarboxylic acid chloride (BTC) and 1,2,4,5-cyclohexanetetracarboxylic acid chloride (HTeC), have been designed and synthesized. The BTC and HTeC monomers can rapidly react with amine mol. at interface to form an aliphatic polyamide nanofilm that is denser than that of TMC based polyamide membrane. The resulting mean effective pore size of the BTC and HTeC polyamide nanofilms is 0.184 nm and 0.197 nm, which is lower than that of the TMC nanofilm at 0.238 nm. Desalination experiments revealed that the aliphatic polyamide membrane shows more than a 98% rejection rate for CaCl2, MgCl2, and MgSO4 and a water flux of 84.4 kg m-2 h-1 MPa-1 (for 2000 ppm MgSO4). Moreover, the ion selectivity of Na+/Mg2+ and Na+/Ca2+ of the BTC membrane is as high as 126 and 31.5, resp. These are much higher than those of the related TMC and com. nanofiltration membranes. Fouling experiments indicate that the flux decline rate (FDR) of the aliphatic polyamide membrane is only 38%, whereas the FDR of the full-aromatic polyamide membrane is 60%. Further investigations confirmed that surface roughness is the main factor affecting the fouling behaviors of polyamide membranes. Our results demonstrate that BTC and HTeC monomers are unique potential materials in the fabrication of nanofiltration membranes used for water treatment such as water softening and ion sieving.

Separation and Purification Technologypublished new progress about Anions (mono and divalent). 4415-87-6 belongs to class tetrahydrofurans, and the molecular formula is C8H4O6, Synthetic Route of 4415-87-6.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Song, Yongzhi; Yuan, Lili; Wang, Zhiyuan; Yang, Shiyong published the artcile< Photo-aligning of polyimide layers for liquid crystals>, Computed Properties of 4415-87-6, the main research area is photoaligning polyimide layer liquid crystal display.

A series of soluble and highly transparent semi-alicyclic polyimides (PIs) with designed flexible linkages have been synthesized derived from an alicyclic aromatic dianhydride (1,2,3,4-cyclobutanetetracarboxylic dianhydride, CBDA) and various aromatic ether-bridged diamines. The semi-alicyclic PIs were evaluated as the photo-alignment layers of liquid crystal (LC) mols. in liquid crystal display (LCD). Exptl. results indicate that the photo-alignment characteristics of LC mols. induced by the photo-aligned PI layers and the electro-optical (EO) properties of the LC cell devices are closely related with PI backbone structures. The retardation of the photo-aligned PI layers is correlated with the UV absorption intensity of PI at 220 to approx. 330 nm. The higher UV absorption intensity PI has, the higher retardation and lower pre-tilt angle the photo-aligned PI layer exhibits. The defect-free and photo-aligned PI layer could result into the uniform LC texture, which is highly desired for in-plane switching (IPS) mode LCD devices. In comparison, PI layer containing trifluoromethyl moiety shows poor photo-aligning performance because of the strong electronic withdrawing effect of the fluorinated linkage.

Polymers for Advanced Technologiespublished new progress about Electrooptical instruments. 4415-87-6 belongs to class tetrahydrofurans, and the molecular formula is C8H4O6, Computed Properties of 4415-87-6.

Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem