Category: 22530-98-9

22530-98-9, Name is 4-Benzyldihydrofuran-2(3H)-one, belongs to Tetrahydrofurans compound, is a common compound. HPLC of Formula: C11H12O2In an article, once mentioned the new application about 22530-98-9.

Radical cyclization on solid support: Synthesis of gamma-butyrolactones

Synthesis of gamma-butyrolactones using radical cyclization on solid-phase has been achieved. Polymer-supported beta-bromoethylacetals were treated with tributyltin hydride in the presence of a catalytic amount of alpha,alpha’- azobisisobutyronitrile to generate intermediate carbon radicals which cyclize onto the intramolecular carbon-carbon double bond. The cyclization products were released by Jones oxidation from resin to give gamma-butyrolactones in good yields.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Related Products of 22530-98-9, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 22530-98-9, 4-Benzyldihydrofuran-2(3H)-one, introducing its new discovery.

Synthesis of optically active beta-benzyl-gamma-butyrolactone through lipase-catalyzed kinetic resolution

The lipase-catalyzed kinetic resolution of the racemic gamma-hydroxy ester 2, coupled with subsequent acid-mediated cyclization, is an effective method for the synthesis of both enantiomers of beta-benzyl-gamma-butyrolactone 1. This enzymatic process affords the product with high enantiomeric excess under mild reaction conditions and does not require optically active starting materials.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Related Products of 22530-98-9. In my other articles, you can also check out more blogs about 22530-98-9

Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

22530-98-9, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.22530-98-9, Name is 4-Benzyldihydrofuran-2(3H)-one, molecular formula is C11H12O2. In a article£¬once mentioned of 22530-98-9

Tetramethylethylene diamine/trimethylsilyl chloride mediated addition of benzyl copper reagents to alpha,beta-unsaturated esters

Several benzylic copper reagents, benzylcopper, 4-methoxybenzylcopper and 1-phenylethylcopper, facilitate the conjugate addition of the corresponding benzyl ligands to alpha,beta-enoates in the presence of tetramethylethylene diamine and trimethylsilyl chloride in high yields.

A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. 22530-98-9, In my other articles, you can also check out more blogs about 22530-98-9

Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem