Some scientific research about 2144-40-3

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In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Safety of (cis-Tetrahydrofuran-2,5-diyl)dimethanol, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 2144-40-3, name is (cis-Tetrahydrofuran-2,5-diyl)dimethanol. In an article£¬Which mentioned a new discovery about 2144-40-3

SALTS OF SUBSTITUTED ALLOPHANATES AND THEIR USE IN DRUGS

The invention relates to salts of substituted allophanates, to methods for producing them, to drugs containing said compounds and to the use of said compounds for producing drugs.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

The important role of (cis-Tetrahydrofuran-2,5-diyl)dimethanol

Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Formula: C6H12O3, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 2144-40-3, in my other articles.

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Ru/MnCo2O4 as a catalyst for tunable synthesis of 2,5-bis(hydroxymethyl)furan or 2,5-bis(hydroxymethyl)tetrahydrofuran from hydrogenation of 5-hydroxymethylfurfural

Manganese and cobalt metals-based mixed oxide (MnCo2O4) spinels supported ruthenium (Ru) nanoparticles, Ru/MnCo2O4, is found to be an active catalyst to execute outstandingly the hydrogenation of 5-hydroxymethylfurfural (HMF) to produce two useful furan diols such as 2,5-bis(hydroxymethyl)furan (BHMF) and 2,5-bis(hydroxymethyl)tetrahydrofuran (BHMTHF) in highly selective fashion without any additive. It could found that Ru/MnCo2O4 was able to catalyze not only the oxidation but also the reduction of HMF due to the redox properties of the MnCo2O4. Moreover, the characterization details responsible for the high activity of this catalyst in the hydrogenation of HMF were investigated by several spectroscopic methods. In order to maximize the products yield and HMF conversion, the effect of reaction variables such as time, temperature, pressure, and various metal oxides supported Ru nanoparticles was also investigated. Furthermore, the reusability tests exhibited that Ru/MnCo2O4 catalyst could be reused at several consecutive cycles, retaining almost its original activity.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

The important role of (cis-Tetrahydrofuran-2,5-diyl)dimethanol

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Recent developments of metallic nanoparticle-graphene nanocatalysts

Graphene-based nanomaterials are promising in a wide range of applications due to their unique structural, chemical and physical properties that have recently led to their investigations as co-catalysts and nanoparticle catalyst templates for organic, electrochemical and photochemical reactions. Herein, we present an overview of hybrid metal nanoparticle-graphene catalysts with specific attention to the most recent achievements since 2015. The state-of-the-art of their synthesis and characterization is also summarized, and the synergistic metallic nanoparticle-graphene interactions and their functions in catalysis are discussed. Finally, challenges and future outlooks for this hot area are envisaged.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Extended knowledge of (cis-Tetrahydrofuran-2,5-diyl)dimethanol

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PROCESS FOR PRODUCING A BIO-BASED POLYETHYLENE TEREPHTHALATE (PET) POLYMER, ENTIRELY FROM BIO-BASED MATERIALS

The invention relates to a process for producing a bio-based polyethylene terephthalate (PET) polymer, from at least one terephthalate compound obtained from at least one bio-based material, and at least one monoethylene glycol compound obtained from at least one bio-based material, Said process comprising the polymerization of the terephthalate compound and of the monoethylene glycol compound in the presence of at least one crystallization retarding compound, Said process being characterized in that the crystallization retarding compound is obtained from at least one bio-based material. The invention also relates to a bio-based PET polymer obtained by said process. Preferably, the process further comprises processing the bio-based PET polymer into a bio-based product such as a bio-based container or a bio-based packaging. The invention also relates to said bio-based product.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Simple exploration of (cis-Tetrahydrofuran-2,5-diyl)dimethanol

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The Synthesis of 5-Hydroxymethylfurfural from Glucose in Biphasic System by Phosphotungstic Acidified Titanium?Zirconium Dioxide

Phosphotungstic acidified titanium?zirconium dioxide catalysts with different loading of phosphotungstic acid (HPA) were synthesized by a precipitation-impregnation method. The phosphotungstic acidified solid acids were characterized by fourier transform infrared spectrometer (FT-IR), X-ray diffraction (XRD), ammonia temperature programmed desorption (NH3-TPD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscope (TEM) techniques. And the catalytic performance of HPA/TiO2?ZrO2 was explored for glucose degradation to 5-hydroxymethylfurfural (5-HMF) in biphasic system, such as the loading of HPA, the molar ratio of TiO2 to ZrO2, reaction time, temperature, amount of catalyst, the volume ratio of VNaCl(aq)/VTHF and magnetic stirring speed. It was found that activity of the catalyst was related to the amount and density of acid site. The optimized yield of 51.3% for 5-HMF and the optimum conversion rate of 95.4% for glucose were achieved by 5% HPA/TiO2?ZrO2. Meanwhile, recycling performance of the catalyst was investigated. And the catalyst had good thermal stability, the yield of 5-HMF was 41.2% and the conversion rate of glucose remained at 85.4% after five cycles.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Awesome Chemistry Experiments For (cis-Tetrahydrofuran-2,5-diyl)dimethanol

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Selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using palladium catalyst supported on mesoporous graphitic carbon nitride

Selective hydrogenation of biomass-derived 5-hydroxymethylfurfural (HMF) to 2,5-dihydroxymethyl-tetrahydrofuran (DHMTHF) with 96% selectivity and a complete HMF conversion is obtained over palladium catalyst supported on mesoporous graphitic carbon nitride (Pd/mpg-C3N4) under pressured hydrogen atmosphere in aqueous media. The excellent catalytic performance of Pd/mpg-C3N4 is attributed to hydrogen bonding-related competitive interactions between reactant HMF and ?intermediate? 2,5-dihydroxymethylfuran (DHMF) with the support mpg-C3N4, which leads to a deep hydrogenation of DHMF to DHMTHF.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Top Picks: new discover of (cis-Tetrahydrofuran-2,5-diyl)dimethanol

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Ni Nanoparticles Inlaid Nickel Phyllosilicate as a Metal-Acid Bifunctional Catalyst for Low-Temperature Hydrogenolysis Reactions

Hydrogenolysis of carbon-oxygen bonds is a versatile synthetic method, of which hydrogenolysis of bioderived 5-hydroxymethylfurfural (HMF) to furanic fuels is especially attractive. However, low-temperature hydrogenolysis (in particular over non-noble catalysts) is challenging. Herein, nickel nanoparticles (NPs) inlaid nickel phyllosilicate (NiSi-PS) are presented for efficient hydrogenolysis of HMF to yield furanic fuels at 130-150 C, being much superior with impregnated Ni/SiO2 catalysts prepared from the same starting materials. NiSi-PS also shows a 2-fold HMF conversion intrinsic rate and 3-fold hydrogenolysis rate compared with the impregnated Ni/SiO2. The superior performance originated from the synergy of highly dispersed nickel NPs and substantially formed acid sites due to coordinatively unsaturated Ni (II) sites located at the remnant nickel phyllosilicate structure, as revealed by detailed characterizations. The model reactions over the other reference catalysts further highlighted the metal-acid synergy for hydrogenolysis reactions. NiSi-PS can also efficiently catalyze low-temperature hydrogenolysis of bioderived furfural and 5-methylfurfural, demonstrating a great potential for other hydrogenolysis reactions.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Extended knowledge of 2144-40-3

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Catalytic routes from renewables to fine chemicals

This paper gives a short review of different catalytic processes for the conversion of terpenes, triglycerides and carbohydrates to valuable chemicals and polymers. Attention is focussed on the new catalytic routes starting from platform molecules derived from renewables and different from the traditional chemical synthesis routes starting from fossil fuels. Also, stress is laid on the green character of these new processes and on the possibility to conduct one-pot process whenever possible.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

More research is needed about 2144-40-3

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Bio-Based Chemicals: Selective Aerobic Oxidation of Tetrahydrofuran-2,5-dimethanol to Tetrahydrofuran-2,5-dicarboxylic Acid Using Hydrotalcite-Supported Gold Catalysts

A new, sustainable catalytic route for the synthesis of tetrahydrofuran-2,5-dicarboxylic acid (THFDCA), a compound with potential application in polymer industry, is presented starting from the bio-based platform chemical 5-(hydroxymethyl)furfural (HMF). This conversion was successfully achieved via oxidation of tetrahydrofuran-2,5-dimethanol (THFDM) over hydrotalcite (HT)-supported gold nanoparticle catalysts (2 wt %) in water. THFDM was readily obtained with high yield (>99%) from HMF at a demonstrated 20 g scale by catalytic hydrogenation. The highest yield of THFDCA (91%) was achieved after 7 h at 110 C under 30 bar air pressure and without addition of a homogeneous base. Additionally, Au-Cu bimetallic catalysts supported on HT were prepared and showed enhanced activity at lower temperature compared to the monometallic gold catalysts. In addition to THFDCA, the intermediate oxidation product with one alcohol and one carboxylic acid group (5-hydroxymethyl tetrahydrofuran-2-carboxylic acid, THFCA) was identified and isolated from the reactions. Further investigations indicated that the gold nanoparticle size and basicity of HT supports significantly influence the performance of the catalyst and that sintering of gold nanoparticles was the main pathway for catalyst deactivation. Operation in a continuous setup using one of the Au-Cu catalysts revealed that product adsorption and deposition also contributes to a decrease in catalyst performance.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Brief introduction of (cis-Tetrahydrofuran-2,5-diyl)dimethanol

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Selective dehydration of glucose to 5-hydroxymethylfurfural on acidic mesoporous tantalum phosphate

Mesoporous tantalum phosphate was prepared from tantalum tartrate and ammonium phosphate monobasic in the presence of an ionic surfactant at room temperature, and subsequent calcined at 550C. This solid exhibits a high specific surface area (256m2g-1) and strong acidity (1.48mmolNH3g-1), and it has been successfully used as solid acid catalyst in the dehydration of glucose to 5-hydroxymethylfurfural (HMF) in a biphasic water/methyl isobutyl ketone medium. By using a glucose:catalyst weight ratio of 3:1, a glucose conversion of 56.3% and a HMF yield of 32.8% were achieved at 170C, and after only 1h of reaction time. The reaction is very selective towards HMF, which is the unique product detected and moreover it is preserved from ulterior hydration to levulinic acid. Fructose was never found as by-product in the reaction. The catalyst is very stable under these experimental conditions, since no leaching of phosphorus or tantalum species to the liquid phase was found. The catalytic performance of this acid solid is well maintained after three catalytic cycles. The high catalytic activity of this mesoporous solid in the dehydration of glucose could be associated to its high acidity and the presence of both Bro?nsted and Lewis acid sites, which are maintained in water.

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Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem