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The aim of this work was to reliably identify odorous compounds of European seabass (Dicentrarchus labrax) after 1, 4 and 15 days of storage in order to find markers of freshness or spoilage. For this purpose, a dynamic headspace gas chromatography olfactometry device (DH-GC-MS/8O) was used with a panel of eight sniffers for comprehensive detection of odorants. One- and two-dimensional gas chromatography (GC-GC-MS/O) coupled with olfactometry and mass spectrometry gave reliable identification. More than 144 volatile compounds were detected in seabass flesh, of which only 13 proved to be odorant (their biochemical origins are discussed): methane-thiobis, thiophene, toluene + butanoic acid ethyl ester, hexanal, 1-hexanol, 1-octen-3-one, 1-octen-3-ol, dimethyl-trisulfide, octanal, 1-nonen-3-ol, (E)-2-nonenal and 2 unknown compounds. Amongst these compounds, only thiophene, hexanal, 1-octen-3-one, dimethyl-trisulfide, and 1-nonen-3-ol are proposed as markers of seabass quality.

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Aroma components from the ripe fruit of Prunus salicina L. cv. Friar and their changes during cold storage were analyzed in this study. Fifty-one volatiles were identified by dichloromethane direct extraction method using gas chromato-graphy?mass spectrophotometry (GC-MS). Their total content was 50.4 mug/g, including alcohols, aldehydes, esters, lactones, acids, ketones, phenols, and small amounts of hydrocarbons and heterocyclic compounds. Nine compounds were determined as the would-be impact odorants of Prunus salicina L. cv. Friar, accounting for 24.7% of contents of total aroma components. According to the size of the aroma indices, their contribution to the aroma was list: (E)-2-hexenal, gamma-dodecalactone, hexyl acetate, butane-2,3-diol, 3-methyl-2-butene-1-ol, hexanal, butyl acetate, 1-butanol, and 2-methyl-1-butanol. Compared with the ripe fruit of Prunus salicina L. cv. Friar, types and relative contents of the would-be impact odorants declined during cold storage at 0Candtheshelf-life period at 20C after harvest. This result showed that low temperature inhibited the synthesis of aroma components to a certain extent. The lack of acetates and lactones, which contributed to fruit aroma largely, was the main reason for fading of fruit flavor after cold storage.

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The pleasant popcorn-like smelling compound 2-acetyl-1-pyrroline (2AP) occurs naturally in many foods but is scarcely used as a flavoring agent due to its great instability. In this work, we evaluate the potential of high amylose corn starch to complex and stabilize 2AP. The methodology was first optimized using model compounds, 2-acetylpyridine and 2-acetyl-2-thiazoline, and then applied to 2AP. Complexes were successfully prepared and characterized using X-ray diffraction, gas chromatography, and differential scanning calorimetry. Loadings of up to 0.504 (±0.071)% 2AP were achieved, and storage studies showed that over half of the flavor was retained after 2 weeks at 0% relative humidity. To our knowledge, this is the first demonstration that 2AP can form amylose inclusion complexes and may lead to a method to effectively stabilize this labile aroma compound.

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Hydroxymethylfurfural (HMF) is a high-value platform chemical derived from renewable resources. In recent years, considerable efforts have been made to produce HMF also at industrial scale, which still faces some challenges regarding yield as well as sustainable and economic process designs. This critical Review evaluates the industrial process development of sustainable biomass conversion to HMF. Qualitative and quantitative guidelines are defined for the technological assessment of the processes described in patent literature. The formation of side products, difficulties in the separation and purification of HMF as well as catalyst regeneration were identified as major challenges in the HMF production. A first small-scale, commercial HMF production plant with a capacity of 300 tHMF per year has been operating in Switzerland since 2014.

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In this research, we applied various CuO-MgO-Al2O3 mixed oxide catalysts prepared by different synthesis methods to lignin depolymerization in supercritical ethanol. It is found that CuO-MgO- Al2O3 catalyst plays a promotional role in producing monomeric compounds from the depolymerization of lignin in supercritical ethanol without supplying the gas phase hydrogen. When it comes to compare the catalyst preparation methods, CuO(30)MgAl(2:1) prepared by co-precipitation (CPT) method showed much higher yield of monomeric compounds and gas phase products than CuO(30)/MgAl(2:1) by incipient wetness impregnation (IWI) method. This is attributed to the formation of highly dispersed CuO species in the former catalyst, as confirmed by XRD analysis. When the acid and base characteristics of the support material were changed by varying the Mg:Al ratio from 2:1 to 2:3, there was no remarkable change in the activity. It can be summarized that the higher dispersion of CuO prepared by CPT method is a more decisive factor to provide the higher yield of monomeric compounds in lignin depolymerization over CuO-MgO-Al2O3 catalyst in supercritical ethanol, while acidity and basicity of the support is not a main factor.

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The difference of volatile components in green, oolong and black teas was studied by using comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GC × GC-TOFMS). Simultaneous distillation extraction was proved to be a suitable technique to extract the analytes with interest. A total of 450 compounds were tentatively identified with comparison to the standard mass spectra in available databases, retention index on the first dimension and structured chromatogram. 33 tea samples, including 12, 12 and 9 samples of green, oolong and black tea were analyzed by using GC × GC-TOFMS. After peak alignment, around 3600 peaks were detected. Partial least squares – discriminant analysis and hierarchical cluster analysis were used to classify these samples, then non-parametric hypothesis test (Mann-Whitney U test) and the variable importance in the projection (VIP) were applied to discover the key components to distinguish the three types of tea with significant difference amongst them. 74 differential compounds are defined to interpret the chemical differences of 3 types of tea. This study shows the power of GC × GC-TOFMS method combined with multivariate data analysis to investigate natural products with high complexity for information extraction.

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The solid phase microextraction (SPME) has been the most used technique for the extraction of volatile compounds from rice because of its easy operation and solvent-free. The extraction parameters, sample mass and incubation temperature, were optimized through a central composite rotational design (CCRD), aiming at maximizing the extraction of 2-acetyl-1-pyrroline (2AP), the main compound responsible for the aroma in aromatic rice, and minimizing the generation of hexanal, a marker of lipid oxidation. Besides, the time of sample incubation and fiber exposure for the extraction of the volatile compounds from rice were determined. The optimized conditions for SPME were: 2.5 g of ground rice in a 20 mL vial, sample incubation at 80 C for 60 min and exposure of the divinylbenzene/carboxene/polydimethylsiloxane (DVB/CAR/PDMS) fiber in the headspace for 10 min. The optimized method was sucessfuly applied to 12 varieties of rice and principal component analysis (PCA) was performed to observe similarities in their volatile profile. A total of 152 volatile compounds were identified among the different rice varieties. From these, 42 were identified in arborio rice, 47 in basmati brand A, 43 in basmati brand B, 55 in black rice, 63 in brown rice, 39 in jamine rice, 50 in parboiled brown rice, 43 in parboiled rice, 54 in red rice, 63 in sasanishiki rice, 46 in white rice and 70 in wild rice.

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Elecroreductive cross-coupling reaction of 3-phenylthioalkanoic acids esters (4a) or quaternary ammonium salts of 3-aminoalkanoic acid esters (4b) with aldehydes gave the corresponding gamma-lactones in one step.The cross-coupling reaction of (4b) with acid anhydrides leading to the formation of the corresponding gamma-keto esters is also described.

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Electroreductive crossed hydrocoupling of alpha,beta-unsaturated esters with aldehydes or ketones in the presence of trimethylchlorosilane afforded gamma-lactones in good yields. Similarly, alpha,beta-unsaturated nitriles gave gamma-hydroxynitriles in high yields.

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The present invention relates to a process for producing aromatics, a process for producing p-xylene and terephthalic acid, and a device for producing aromatics. The process for producing aromatics at least comprises a step of producing C8 olefin from a compound having a lactone group and a step of producing aromatics from the C8 olefin. The process for producing aromatics has the characters of high yield of aromatics and high selectivity to xylene.

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