Effect of various phosphate-containing substances on the rate of vanadyl sulfate oxidation by potassium permanganate was written by Kriss, E. E.; Yatsimirskii, K. B.. And the article was included in Zhurnal Neorganicheskoi Khimii in 1969.Recommanded Product: Thymidine 5′-(tetrahydrogen triphosphate) xsodium salt The following contents are mentioned in the article:
VOSO4 oxidation by KMnO4 in H2SO4 solution was studied by stopped-flow method. The oxidation was accomplished within few sec. and proceeded in 2 stages of different reaction velocity. The 1st stage is considered as an inductive period. The rate constant and energy of activation of the 2nd stage reaction are (1 ± 0.1) × 102 l. mole-1 sec.-1 and 8.2 kcal./mole, resp. Reaction rate was independent of H2SO4 or vanadium (V) concentrations (at 5 × 10-2-2 × 10-3M NH4VO3) but depended on MnO4- and VO2+ concentrations Phosphate-containing compounds (inorganic or purine and pyrimidine derivatives of phosphoric acid) accelerated the oxidation and in their presence the reaction depended also on the P-compound concentration, hence was a 3rd-order reaction. This study involved multiple reactions and reactants, such as Thymidine 5′-(tetrahydrogen triphosphate) xsodium salt (cas: 18423-43-3Recommanded Product: Thymidine 5′-(tetrahydrogen triphosphate) xsodium salt).
Thymidine 5′-(tetrahydrogen triphosphate) xsodium salt (cas: 18423-43-3) belongs to tetrahydrofuran derivatives. Solid acid catalysis, and the advantages often associated with their use, have been proved equally efficient for the synthesis of tetrahydrofurans or furans. It is more basic than diethyl ether and forms stronger complexes with Li+, Mg2+, and boranes. It is a popular solvent for hydroboration reactions and for organometallic compounds such as organolithium and Grignard reagents.Recommanded Product: Thymidine 5′-(tetrahydrogen triphosphate) xsodium salt
18423-43-3;Thymidine 5′-(tetrahydrogen triphosphate) xsodium salt;The future of 18423-43-3;New trend of C10H14N2Na3O14P3;function of 18423-43-3