Li, Feng; Jiang, Shanshan; Zhu, Tianhan; Wang, Yue; Huang, Tao; Li, Cuiqin published the artcile< Organodiphosphonate Metal-Organic Frameworks Derived Ni-P@C Catalyst for Hydrogenation of Furfural>, Electric Literature of 97-99-4, the main research area is organodiphosphonate metal organic framework furfural hydrogenation.
Tetra-Et p-xylenediphosphate is used as the organic ligand to prepare the Ni-P-MOFs material belonging to the category of organic phosphoric acids, through pyrolysis and in-situ reduction reaction of Ni-P-MOFs material during the high-temperature carbonization process, Ni-P@C catalyst with graphitized carbon-covering Ni2P particles is prepared Compared with Ni-P catalyst prepared through coprecipitation method, Ni-P@C catalyst prepared with Ni-P-MOFs material can obviously decrease the formation temperature of Ni2P active phase and retain the schistose morphol. of the Ni-P-MOFs material, which is of high specific area, and meanwhile effectively suppresses the agglomeration of Ni2P particles. It is indicated by research on furfural hydrogenation performance that, Ni-P@C catalyst presents a high activity and stability in furfural hydrogenation. Products of furfural hydrogenation catalyzed by Ni-P@C catalyst mainly contain furfuryl alc., 2-methylfuran and 2-methyltetra hydrofuran, and the reaction temperature and reaction time have great influence on the distribution of products. The carbon-covering structure of Ni-P@C catalyst can effectively protect the active components of Ni2P, thus presenting a high stability and good reusability.
ChemistrySelect published new progress about Crystallinity. 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Electric Literature of 97-99-4.
Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem