So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Jiang, Zhenzhen; Fan, Lihui; Zhou, Ping; Xu, Tingting; Chen, Jingxian; Hu, Simin; Chen, De-Li; He, Yabing researched the compound: Methyl 6-bromonicotinate( cas:26218-78-0 ).Reference of Methyl 6-bromonicotinate.They published the article 《An N-oxide-functionalized nanocage-based copper-tricarboxylate framework for the selective capture of C2H2》 about this compound( cas:26218-78-0 ) in Dalton Transactions. Keywords: oxide functionalized nanocage copper tricarboxylate framework selective capture acetylene. We’ll tell you more about this compound (cas:26218-78-0).
The selective capture of C2H2 from C2H2-C2H4 and C2H2-CO2-CH4 mixtures is a very essential but highly challenging process during C2H4 and C2H2 purification in the chem. industry. In this work, by virtue of using oxygen-atom-rich C2H2 recognition sites, we, for the first time, designed and synthesized an N-oxide-functionalized tricarboxylate ligand and utilized it to successfully construct a copper-based MOF. N-Oxide functionalization exerted a significant effect on the ligand conformation, thus resulting in a new topol. network that is different from that of the unoxidized parent compound With a moderate surface area and the immobilization of N-oxide functionality and carboxylate oxygen atoms in two nanocages, the title MOF exhibited promising potential for the multifunctional separation of C2H2/C2H4 and C2H2/CO2/CH4 mixtures under ambient conditions, as shown by pure-composition isotherm measurements, IAST predictions, and mol. modeling studies.
In addition to the literature in the link below, there is a lot of literature about this compound(Methyl 6-bromonicotinate)Reference of Methyl 6-bromonicotinate, illustrating the importance and wide applicability of this compound(26218-78-0).
Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem