Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 26218-78-0, is researched, Molecular C7H6BrNO2, about Functionalization of Bis-Diazaphospholene P-P Bonds with Diverse Electrophiles, the main research direction is crystal structure mol phosphorus nitrogen heterocycle diazaphospholene preparation; functionalization bisdiazaphospholene phosphorus bond electrophile.Recommanded Product: 26218-78-0.
Phosphorus-sp3 or -sp2 carbon bonds are readily formed by the reaction of bis-diazaphospholenes with several classes of electrophiles. These reactions result in cleavage of the phosphorus-phosphorus bond and formation of functionalized diazaphospholenes. The reactions proceed rapidly, without catalysis. Exptl. evidence with aryl and alkyl halides suggests the intermediacy of radicals in some cases, however other evidence suggests either radical or polar mechanisms may be operative for certain substrates, with a dependence on reaction conditions. In three cases, the product aryl diazaphospholenes have been shown to transfer the aryl substituent to electrophiles. These results reveal that diazaphospholene dimers are potent participants in radical chem. with organic substrates at room temperature without requiring chem. initiators.
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Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem