Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 4221-99-2, is researched, SMILESS is C[C@H](O)CC, Molecular C4H10OJournal, Article, Angewandte Chemie, International Edition called Controlling the Multiple Chiroptical Inversion in Biphasic Liquid-Crystalline Polymers, Author is Cheng, Xiaoxiao; Miao, Tengfei; Ma, Yafei; Zhu, Xiaoyan; Zhang, Wei; Zhu, Xiulin, the main research direction is chirality self assembly liquid crystalline aggregation supramol stacking chiroptical; azobenzene; chirality; liquid-crystalline polymers; polymerization-induced self-assembly; supramolecular chemistry.Quality Control of (S)-Butan-2-ol.
While controlling the chirality and modulating the helicity is a challenging task, it attracts great research interest for gaining a better understanding of the origin of chirality in nature. Herein, structurally similar azobenzene (Azo) vinyl monomers were designed in which the alkyl chains comprised the chiral stereocenter with different achiral tail lengths. Combining the synchronous polymerization, supramol. stacking and self-assembly, the multiple chiroptical inversion of the Azo-polymer supramol. assemblies can be modulated by the tail length and DP of Azo blocks during in situ polymerization The DP-, UV light-, temperature-, aging time-dependent chiroptical properties and liquid-crystalline (LC) characterization indicated that the amorphous-to-LC phase transition and biphasic LC interconversion allow the transcription of intra-chain π-π stacking, inter-chain H- and J-aggregation, thereby controlling the dynamic multiple reversal of supramol. chirality.
There is still a lot of research devoted to this compound(SMILES：C[C@H](O)CC)Quality Control of (S)-Butan-2-ol, and with the development of science, more effects of this compound(4221-99-2) can be discovered.
Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem