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Cyclobutanes derived from [2+2] photocycloaddition reactions of tetronic acid esters were subjected to free-radical fragmentation reactions. The product formation was strongly dependent on the relative stabilities of the intermediate radicals, thus leading to either an oxepane or a methylenetetrahydrofuran in good yields. Georg Thieme Verlag Stuttgart.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.name: Furan-2,4(3H,5H)-dione, you can also check out more blogs about4971-56-6
Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem