Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 3188-00-9, Name is 2-Methyltetrahydrofuran-3-one, SMILES is CC1C(CCO1)=O, belongs to tetrahydrofurans compound. In a document, author is El-Agamey, Ali, introduce the new discover, Product Details of 3188-00-9.
Carotenoid radical ions: A laser flash photolysis study
Laser excitation of a single precursor, namely 2-hydroxy-4′-(2- hydroxyethoxy)-2-methylpropiophenone (HHEMP), has been used for generating the radical cations and radical anions of various carotenoids in methanol. In the presence of oxygen, laser excitation of HHEMP undergoes an efficient alpha-cleavage reaction (Norrish type I) to form acyl radicals, which react with O-2, in a nearly diffusion-controlled reaction, to form their corresponding strong oxidizing acylperoxyl radicals (RO2 center dot) (E = similar to 1.1 V (v SHE)), which are capable of oxidizing almost all carotenoids. Under argon-saturated conditions and in the presence of strong base (0.01 M NaOH or tetrabutylammonium hydroxide (TBAOH)), the initially formed 2-hydroxy-2-propyl radical (ACH(center dot)), generated after LFP of HHEMP, is deprotonated to form the strong reducing acetone ketyl radical (AC(center dot-)) (E {acetone/AC(center dot-)} = – 2.1 V (v SHE)), which is capable of reducing all carbonyl-containing carotenoids. To validate this new proposed approach, retinal and beta-apo-8′-carotenal (APO), with known spectroscopic data, were investigated in methanol, acetonitrile and tetrahydrofuran (THF). In addition, the radical ions of newly investigated carotenoids, namely 4-oxo-beta-apo-15′-carotenoic acid (4-oxo-15′), crocetindial, 4-oxo-beta-apo-10′-carotenoic acid ethyl ester (4-oxo-10′) and 4-oxo-beta-apo-8′-carotenoic acid ethyl ester (4-oxo-8′) have been reported. Moreover, the scope of this approach has been extended to investigate the radical ions of chlorophyll b.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 3188-00-9 is helpful to your research. Product Details of 3188-00-9.
Reference:
Tetrahydrofuran – Wikipedia,
,Tetrahydrofuran | (CH2)3CH2O – PubChem