Synthesis and Glycosylation Properties of C6-Silylated Ido- and Gluco-Pyranosyl Donors was written by Alvarez-Martinez, Ignacio;Pedersen, Christian Marcus. And the article was included in European Journal of Organic Chemistry in 2020.Reference of 582-52-5 This article mentions the following:
Silyl groups are widely used as alc. protecting groups and their study has provided insight on some very remarkable structure and reactivity features within carbohydrate chem. However, not much work has been put into the effect on the reactivity of silyl groups directly attached to the sugar carbon chain. In this work, we have developed a synthetic methodol. to obtain both
(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol (cas: 582-52-5) belongs to tetrahydrofuran derivatives. Solid acid catalysis, and the advantages often associated with their use, have been proved equally efficient for the synthesis of tetrahydrofurans or furans. THF (Tetrahydrofuran) is also used as a starting material for the synthesis of poly(tetramethylene ether) glycol (PTMG), etc.Reference of 582-52-5
Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem