Untargeted Metabolomics Reveals Metabolic Changes Linked to Bulb Purpling in Garlic (Allium sativum L.) was written by Leite, Victor S. A.;Reis, Marcelo R.;Pinto, Frederico G.. And the article was included in ACS Food Science & Technology in 2021.Name: (2R,3R,4S,5S,6R)-2-(((2S,3S,4S,5R)-2-((((2R,3S,4S,5R)-3,4-Dihydroxy-2,5-bis(hydroxymethyl)tetrahydrofuran-2-yl)oxy)methyl)-3,4-dihydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol This article mentions the following:
Garlic (Allium sativum L.) is a vegetable known worldwide, mainly for its characteristic aroma and flavor and for exhibiting several medicinal properties. This culture has significant economic and social relevance in the world agricultural scenario. Most of the garlic production is sold in fresh bulbs, where for some countries the more purple skin bulbs are more valued in the market. However, there is still no consensus about the factors that intensify the purple color of the garlic bulbs. Here, we employed gas chromatog.-mass spectrometry-based untargeted metabolomics to study the metabolome of dark and light purple garlics. Multivariate statistical anal. revealed distinct metabolite signatures between these garlic groups. As metabolic changes play an important factor in changes in the phenotype of cells or an organism, this report presents a fundamental approach for supporting garlic producers in understanding the factors that intensify the purplish color of garlic bulbs, paving the way for safer garlic production with dark purple bulbs. In addition, the medicinal properties of dark purple garlic were greater than that of the light purple garlic, presenting greater abundance in organosulfur compounds Overall, the data suggest that some organic acid and fatty acids such as malonic acid and docosanoic acid are the key differentiating factors between dark and light purple garlics. In the experiment, the researchers used many compounds, for example, (2R,3R,4S,5S,6R)-2-(((2S,3S,4S,5R)-2-((((2R,3S,4S,5R)-3,4-Dihydroxy-2,5-bis(hydroxymethyl)tetrahydrofuran-2-yl)oxy)methyl)-3,4-dihydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (cas: 470-69-9Name: (2R,3R,4S,5S,6R)-2-(((2S,3S,4S,5R)-2-((((2R,3S,4S,5R)-3,4-Dihydroxy-2,5-bis(hydroxymethyl)tetrahydrofuran-2-yl)oxy)methyl)-3,4-dihydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol).
(2R,3R,4S,5S,6R)-2-(((2S,3S,4S,5R)-2-((((2R,3S,4S,5R)-3,4-Dihydroxy-2,5-bis(hydroxymethyl)tetrahydrofuran-2-yl)oxy)methyl)-3,4-dihydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (cas: 470-69-9) belongs to tetrahydrofuran derivatives.Tetrahydrofuran has many industry uses as a solvent including in natural and synthetic resins, high polymers, fat oils, rubber, polymer. Tetrahydrofuran reaction with hydrogen sulfide: In the presence of a solid acid catalyst, tetrahydrofuran reacts with hydrogen sulfide to give tetrahydrothiophene.Name: (2R,3R,4S,5S,6R)-2-(((2S,3S,4S,5R)-2-((((2R,3S,4S,5R)-3,4-Dihydroxy-2,5-bis(hydroxymethyl)tetrahydrofuran-2-yl)oxy)methyl)-3,4-dihydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol
Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem