Zavgorodnii, S.’s team published research in Tetrahedron Letters in 32 | CAS: 87865-78-9

Tetrahedron Letters published new progress about 87865-78-9. 87865-78-9 belongs to tetrahydrofurans, auxiliary class Nucleosides and Nucleotides,Nucleoside Analogues, name is N-(9-((6aR,8R,9R,9aS)-9-Hydroxy-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocin-8-yl)-6-oxo-6,9-dihydro-1H-purin-2-yl)isobutyramide, and the molecular formula is C12H9NO, Synthetic Route of 87865-78-9.

Zavgorodnii, S. published the artcile1-Alkylthioalkylation of nucleoside hydroxyl functions and its synthetic applications: a new versatile method in nucleoside chemistry, Synthetic Route of 87865-78-9, the publication is Tetrahedron Letters (1991), 32(51), 7593-6, database is CAplus.

Treatment of appropriately protected nucleosides I (B = Thy, BzCyt, BzAde, IbGua; R = H) with a mixture of acetic acid, acetic anhydride and dialkyl sulfoxide was shown to give O-(1-alkylthioalkylated) nucleosides I (R = CH2SMe) that were oxidized to the corresponding sulfoxides and sulfones I [R = CH2S(O)nMe, n = 1, 2], or converted via O-halomethyl derivatives I (R = CH2Br, CH2Cl) to various O-substituted nucleosides, e.g., II, [B1 = Thy, Cyt, Ade, Gua; R1 = CH2F, CH2N3, CH2CN, CH2OMe, CH2P(O)(OH)2].

Tetrahedron Letters published new progress about 87865-78-9. 87865-78-9 belongs to tetrahydrofurans, auxiliary class Nucleosides and Nucleotides,Nucleoside Analogues, name is N-(9-((6aR,8R,9R,9aS)-9-Hydroxy-2,2,4,4-tetraisopropyltetrahydro-6H-furo[3,2-f][1,3,5,2,4]trioxadisilocin-8-yl)-6-oxo-6,9-dihydro-1H-purin-2-yl)isobutyramide, and the molecular formula is C12H9NO, Synthetic Route of 87865-78-9.

Referemce:
https://en.wikipedia.org/wiki/Tetrahydrofuran,
Tetrahydrofuran | (CH2)3CH2O – PubChem