Interaction of Pd2 + complexes of 2,6-disubstituted pyridines with nucleoside 5′-monophosphates was written by Golubev, Oleg; Lonnberg, Tuomas; Lonnberg, Harri. And the article was included in Journal of Inorganic Biochemistry on October 31,2014.Related Products of 550-33-4 The following contents are mentioned in the article:
To learn more about the underlying principles of metal ion-mediated recognition of nucleic acid bases, PdCl+ complexes of six 2,6-disubstituted pyridines, viz. pyridine-2,6-dicarboxamide, its N2,N6-dimethyl and N2,N6-diisopropyl derivatives, 6-carbamoylpyridine-2-carboxylic acid, 6-aminomethylpyridine-2-carboxamide and its N2-Me derivative, were prepared and their interaction with nucleoside 5′-monophosphate (NMP) was studied by 1H NMR spectroscopy in D2O at pH 7.2. The binding sites within the nucleobases were assigned on the basis of Pd2 + induced changes in chem. shifts of the base moiety proton resonances. The mole fractions of NMPs engaged in mono- or dinuclear Pd2 + complexes were determined at various concentrations by comparing the intensities of the aromatic and anomeric protons of the complexed and uncomplexed NMPs. Some of the pyridine complexes showed moderate discrimination between the NMPs. This study involved multiple reactions and reactants, such as (2R,3S,4R,5R)-2-(Hydroxymethyl)-5-(9H-purin-9-yl)tetrahydrofuran-3,4-diol (cas: 550-33-4Related Products of 550-33-4).
(2R,3S,4R,5R)-2-(Hydroxymethyl)-5-(9H-purin-9-yl)tetrahydrofuran-3,4-diol (cas: 550-33-4) belongs to tetrahydrofuran derivatives. Solid acid catalysis, and the advantages often associated with their use, have been proved equally efficient for the synthesis of tetrahydrofurans or furans. Commercial tetrahydrofuran contains substantial water that must be removed for sensitive operations, e.g. those involving organometallic compounds. Although tetrahydrofuran is traditionally dried by distillation from an aggressive desiccant, molecular sieves are superior.Related Products of 550-33-4
550-33-4;(2R,3S,4R,5R)-2-(Hydroxymethyl)-5-(9H-purin-9-yl)tetrahydrofuran-3,4-diol;The future of 550-33-4;New trend of C10H12N4O4 ;function of 550-33-4