Poudel, Pramod Prasad; Arimitsu, Kenji; Yamamoto, Kana published the artcile< Self-assembled ion-pair organocatalysis - asymmetric Baeyer-Villiger oxidation mediated by flavinium-cinchona alkaloid dimer>, Recommanded Product: (R)-tert-Butyl (5-oxotetrahydrofuran-3-yl)carbamate, the main research area is flavinium cinchona alkaloid dimer organocatalysis asym Baeyer Villiger oxidation.
An ion-pair catalyst generated by assembly of a chiral flavinium and a cinchona alkaloid dimer for use in asym. Baeyer-Villiger oxidation is presented. Ion-pair formation is essential for enhancing the catalytic activity and stereoselectivity. The catalyst is applicable to structurally diverse 3-substituted cyclobutanones, providing good to excellent enantioselectivities (up to 98 : 2 e.r.). This study provides the first example of self-assembly of a flavin derivative and a base to form a chiral reaction site that enables a highly stereoselective reaction to occur.
Chemical Communications (Cambridge, United Kingdom) published new progress about Baeyer-Villiger oxidation. 137105-97-6 belongs to class tetrahydrofurans, and the molecular formula is C9H15NO4, Recommanded Product: (R)-tert-Butyl (5-oxotetrahydrofuran-3-yl)carbamate.
Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem