Shibutani, Shotaro; Kodo, Taiga; Takeda, Mitsutaka; Nagao, Kazunori; Tokunaga, Norihito; Sasaki, Yusuke; Ohmiya, Hirohisa published the artcile< Organophotoredox-Catalyzed Decarboxylative C(sp3)-O Bond Formation>, Electric Literature of 97-99-4, the main research area is ether secondary amine thioether preparation; alc amine thiol dioxoisoindolinyl carboxylate photoredox decarboxylative coupling.
This manuscript reports a visible-light-mediated organosulfide catalysis that enables the decarboxylative coupling between simple aliphatic alc. and tertiary or secondary alkyl carboxylic acid-derived redox active esters to produce a C(sp3)-O-C(sp3) fragment. Results of the coupling using other heteroatom nucleophiles such as water, amides, and thiols are also described.
Journal of the American Chemical Society published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 97-99-4 belongs to class tetrahydrofurans, and the molecular formula is C5H10O2, Electric Literature of 97-99-4.
Referemce:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem