Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 26218-78-0, is researched, Molecular C7H6BrNO2, about Functionalization of bis-diazaphospholene P-P bonds with diverse electrophiles, the main research direction is functionalization diazaphospholene dimer electrophile; phosphorus bond cleavage diazaphospholene dimer electrophile; crystal mol structure diazaphospholene dimer functionalized product.Electric Literature of C7H6BrNO2.
Readily prepared bis-diazaphospholenes are shown to react with several classes of electrophiles, resulting in cleavage of the phosphorus-phosphorus bond and formation of functionalized diazaphospholenes. Phosphorus – sp3 or sp2 carbon and phosphorus – sulfur bonds were formed using this protocol. Exptl. evidence with aryl and alkyl halides suggests the intermediacy of radicals in some cases, however other evidence suggests either radical or polar mechanisms may be operative for certain substrates, with a dependence on reaction conditions. In some cases, the substituted diazaphospholenes can transfer the substituent to electrophiles via previously unknown reactions. These results show diazaphospholene dimers are potent participants in radical chem. at room temperature without requiring chem. initiators.
Different reactions of this compound(Methyl 6-bromonicotinate)Electric Literature of C7H6BrNO2 require different conditions, so the reaction conditions are very important.
Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem