Application In Synthesis of (S)-Butan-2-ol. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: (S)-Butan-2-ol, is researched, Molecular C4H10O, CAS is 4221-99-2, about Preliminary exploration on enzyme-promoted asymmetric biomimetic synthesis of resveratrol dimers. Author is Lei, Tian; Guan, Xingchao; Kang, Xiaodong; Wang, Yuefei; Han, Li; Li, Wenling.
The asym. biomimetic synthesis of resveratrol dimers was preliminarily explored using the enzyme-mediated oxidative coupling reactions of chiral resveratrol derivatives as the key step. The horseradish peroxidase-H2O2-promoted oxidations of 11,13-di-sec-butylresveratrol ether and 3,5-dibromoresveratrol di-sec-Bu ethers generated an 8-5-coupled intermediate and several 8-8-coupled dimeric mixtures, resp. The acid-catalyzed debutylation of the coupling dimers and hydrogenolytic debromination synthesized natural (+)-δ-viniferin (I) and unnatural (+)-isoquadrangularin A (II) with undetermined stereoisomer ratio.
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Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem