The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 2-Amino-5-chlorobenzaldehyde(SMILESS: NC1=CC=C(Cl)C=C1C=O,cas:20028-53-9) is researched.Application of 3066-84-0. The article 《Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems》 in relation to this compound, is published in Journal of the American Chemical Society. Let’s take a look at the latest research on this compound (cas:20028-53-9).
Cu/TEMPO catalyst systems promote efficient aerobic oxidation of sterically unhindered primary alcs. and electronically activated substrates, but they show reduced reactivity with aliphatic and secondary alcs. Here, we report a catalyst system, consisting of (MeObpy)-CuI(OTf) and ABNO (MeObpy = 4,4′-dimethoxy-2,2′-bipyridine; ABNO = 9-azabicyclo[3.3.1]nonane N-oxyl), that mediates aerobic oxidation of all classes of alcs., including primary and secondary allylic, benzylic, and aliphatic alcs. with nearly equal efficiency. The catalyst exhibits broad functional group compatibility, and most reactions are complete within 1 h at room temperature using ambient air as the source of oxidant.
Here is just a brief introduction to this compound(20028-53-9)Electric Literature of C7H6ClNO, more information about the compound(2-Amino-5-chlorobenzaldehyde) is in the article, you can click the link below.
Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem