Application In Synthesis of 1-Hexyl-3,7-dimethyl-1H-purine-2,6(3H,7H)-dione. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 1-Hexyl-3,7-dimethyl-1H-purine-2,6(3H,7H)-dione, is researched, Molecular C13H20N4O2, CAS is 1028-33-7, about Synthesis and Characterization of Novel β-Bis(N,N-diarylamino)-Substituted Porphyrin for Dye-Sensitized Solar Cells under 1 sun and Dim Light Conditions. Author is Reddy, Kamani Sudhir K.; Liu, Yu-Chieh; Chou, Hsien-Hsin; Kala, Kannankutty; Wei, Tzu-Chien; Yeh, Chen-Yu.
The authors synthesized a novel porphyrin dye named SK7, which contains two N,N-diarylamino moieties at two β-positions as electron-donating units and one carboxy phenylethynyl moiety at the meso-position as an electron-withdrawing, anchoring group. This novel dye was tested for the application in dye-sensitized solar cells. The light-harvesting behavior of SK7 and YD2 was studied using UV-visible absorption and d. functional calculation The electron transport properties at the TiO2/dye/electrolyte interface for SK7- and YD2-based devices were evaluated by electrochem. impedance spectroscopy. X-ray crystallog. characterization was conducted to understand the influence of two N,N-diarylamino units at two β-positions. The power conversion efficiencies of ∼6.54% under 1 sun illumination (AM 1.5 G) and ∼19.72% under a T5 light source were noted for the SK7 dye. The performance of SK7 is comparable to that of dye YD2, which contains only one N,N-diarylamino moiety at the meso-position (∼7.78 and 20.00% under 1 sun and T5 light, resp.).
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