We’ll be discussing some of the latest developments in chemical about CAS: 13031-04-4. Computed Properties of C6H8O3
The Baylis-Hillman reaction of acrylonitrile, methyl acrylate, and acrolein with several cyclic alpha-dicarbonyl compounds was investigated.Whereas acrylonitrile reacted with most of these ketones, giving good yields of the expected 1′-cyanovinyl carbinols, the more sterically demanding methyl acrylate failed to undergo the reaction.Attempted Baylis-Hillman reaction of acrolein with the 1,2-dicarbonyl substrates usually resulted in polymers but, in two cases, the desired alpha-substituted acroleins were obtained.An alternative route to such compounds was developed, employing a Grignard-allylic oxidation sequence.In bioassays, some of the products, embodying the functionality believed responsible for the phytotoxicity of the sesquiterpene bipolaroxin, inhibited germination of lettuce seeds.This activity diminished with time. – Key words: Baylis-Hillman, acrylonitrile, acrylate, acrolein, alpha-dicarbonyl, bipolaroxin, phytotoxicity.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C6H8O3, you can also check out more blogs about13031-04-4
Reference：
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem