Synthetic Route of 89364-31-8, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.89364-31-8, Name is Tetrahydrofuran-3-carboxylic acid, molecular formula is C5H8O3. In a Article,once mentioned of 89364-31-8
Here, we describe the successful application of novel glucofuranose-derived 1,3-diphosphites in the rhodium-catalysed asymmetric hydroformylation of vinyl acetate, 2,5-dihydrofuran and 2,3-dihydrofuran. In the hydroformylation of vinyl acetate, total regioselectivity and high ee (up to 73%) were obtained. When 2,3- and 2,5-dihydrofuran were the substrates, total chemo- and regioselectivities were achieved together with ees up to 88%. These results correspond to the highest ee values reported to date in the asymmetric hydroformylation of these substrates. The HP-NMR studies of the [RhH(CO) 2(L)] species (L=15 and 17) demonstrated that both ligands coordinate to the Rh centre in an eq-eq fashion. The complex [RhH(CO)2(15)] was detected as a single isomer with characteristic features of eq-eq coordination. However, the broadening of the corresponding signals indicated that this species is rapidly interchanging in solution. In contrast, complex [RhH(CO) 2(17)] was detected as a mixture of two conformational isomers at low temperature due to the greater flexibility of the monocyclic backbone of this ligand.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 89364-31-8
Reference:
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem