Related Products of 2144-40-3, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 2144-40-3, Name is (cis-Tetrahydrofuran-2,5-diyl)dimethanol, molecular formula is C6H12O3. In a Article£¬once mentioned of 2144-40-3
Ni Nanoparticles Inlaid Nickel Phyllosilicate as a Metal-Acid Bifunctional Catalyst for Low-Temperature Hydrogenolysis Reactions
Hydrogenolysis of carbon-oxygen bonds is a versatile synthetic method, of which hydrogenolysis of bioderived 5-hydroxymethylfurfural (HMF) to furanic fuels is especially attractive. However, low-temperature hydrogenolysis (in particular over non-noble catalysts) is challenging. Herein, nickel nanoparticles (NPs) inlaid nickel phyllosilicate (NiSi-PS) are presented for efficient hydrogenolysis of HMF to yield furanic fuels at 130-150 C, being much superior with impregnated Ni/SiO2 catalysts prepared from the same starting materials. NiSi-PS also shows a 2-fold HMF conversion intrinsic rate and 3-fold hydrogenolysis rate compared with the impregnated Ni/SiO2. The superior performance originated from the synergy of highly dispersed nickel NPs and substantially formed acid sites due to coordinatively unsaturated Ni (II) sites located at the remnant nickel phyllosilicate structure, as revealed by detailed characterizations. The model reactions over the other reference catalysts further highlighted the metal-acid synergy for hydrogenolysis reactions. NiSi-PS can also efficiently catalyze low-temperature hydrogenolysis of bioderived furfural and 5-methylfurfural, demonstrating a great potential for other hydrogenolysis reactions.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Related Products of 2144-40-3. In my other articles, you can also check out more blogs about 2144-40-3
Reference£º
Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem