Can You Really Do Chemisty Experiments About 79-50-5

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79-50-5, Name is 3-Hydroxy-4,4-dimethyldihydrofuran-2(3H)-one, molecular formula is C6H10O3, Recommanded Product: 3-Hydroxy-4,4-dimethyldihydrofuran-2(3H)-one, belongs to Tetrahydrofurans compound, is a common compound. In a patnet, author is Deng, Yong-Kai, once mentioned the new application about 79-50-5.

Preparation of a Lanthanide-Titanium Oxo Cluster-Polymer Composite by Cu-I-Catalyzed Click Chemistry

Incorporating metal clusters within the skeleton of the organic polymers through a click reaction cannot only effectively prepare cluster-polymer composites, but also effectively avoid the cluster aggregation. Herein, an azide-containing lanthanide-titanium oxo cluster of Eu8Ti10-N-3 (Eu8Ti10-N-3=[Eu8Ti10(mu(3)-O)(14)(H2O)(4)(OAc)(2)(tbba)(30)(paza)(4)(THF)(2)].4 THF.8 H2O (1), Htbba=4-tert-butylbenzoic acid, Hpaza=4-azidobenzoate, HOAc=acetic acid, THF=tetrahydrofuran) through an in situ solvothermal reaction of 4-azidobenzoic acid and 4-tert-butylbenzoic acid. Reaction of 1 with PEG (PEG=methoxypoly(ethyleneglycol)alkyne, 2000 g mol(-1)) through Cu-I-catalyzed click chemistry generates a lanthanide-polymer composite of Eu8Ti10-N-3@PEG (2). Investigation with IR, H-1 NMR and ICP-OES of 2 indicates that the structural integrity of 1 is maintained in 2. Study of the luminescent properties of 1 and 2 reveals that the quantum yield of 1 itself basically remains unchanged in 2. Significantly, the formation of 2 cannot only effectively prevent the cluster 1 from aggregation, but also greatly enhance its solubility and adhesion to the substrate. Owing to the solubility and adhesion of luminescent materials being the key to their practical application, present work is thus of great significance for the development of metal cluster-polymer composite luminescent materials.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 79-50-5 help many people in the next few years. Recommanded Product: 3-Hydroxy-4,4-dimethyldihydrofuran-2(3H)-one.

Reference:
Tetrahydrofuran – Wikipedia,
,Tetrahydrofuran | (CH2)3CH2O – PubChem