Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 79-50-5, Name is 3-Hydroxy-4,4-dimethyldihydrofuran-2(3H)-one. In a document, author is Chen, Ji, introducing its new discovery. Application In Synthesis of 3-Hydroxy-4,4-dimethyldihydrofuran-2(3H)-one.
Electrolyte design for Li metal-free Li batteries
Li metal, with the lowest thermodynamically achievable negative electrochemical potential and the highest specific capacity (3860 mAh g(-1)), is the ultimate anode choice for Li batteries. However, the highest reported Li plating/stripping Coulombic efficiency (CE) of 99.5% after extensive efforts is still too low for the Li metal-free (all the Li metal in cycling comes from cathode, without anode prelithiation) Li metal batteries. The low CE is attributed to both non-uniform Li plating/stripping on the lithiophobic Cu current collector and Li dendrite growth through lithiophilic organic-inorganic solid electrolyte interphase (SEI) formed in carbonate electrolytes. Here, we use a lithiophilic Bismuth graphite blend (Bi-Gr) substrate to replace lithiophobic Cu current collector to seed a uniform Li nucleation, and form a lithiophobic LiF-rich SEI rather than lithiophilic organic-rich SEI to suppress Li dendrite growth. Molecular dynamics simulations reveal the preferential reduction of anions in 2.0 M LiPF6 in tetrahydrofuran/2-methyl tetrahydrofuran (2.0 M LiPF6-mixTHF) electrolyte to generate LiF-rich SEI on plated Li. Bi-Gr substrate and 2.0 M LiPF6-mixTHF electrolyte enable the Li anodes to achieve a record high CE of 99.83% at a high capacity of 1.0 mAh cm(-2) and current of 0.5 mA cm(-2). The Bi particles serve as dispersed nucleation centers that promote uniform Li deposition with strong adhesion to the substrate to avoid dead Li, while the lithiophobic LiF-rich SEI promotes lateral Li growth and suppresses the vertical Li dendrite growth even at a high current density of 3.0 mA cm(-2) and high areal capacities of 3.0 mAh cm(-2). The regulation of Li nucleation and growth enables the Li metal-free LiFePO4 full cells to achieve 100 cycles at a practical areal capacity of >2.0 mAh cm(-2). This manuscript highlights the benefits of simultaneous substrate design to improve Li nucleation and electrolyte design to promote lithiophobic SEI growth, enabling a promising and practical route Li metal-free Li metal batteries.
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Reference:
Tetrahydrofuran – Wikipedia,
,Tetrahydrofuran | (CH2)3CH2O – PubChem