97-99-4, Name is (Tetrahydrofuran-2-yl)methanol, molecular formula is C5H10O2, Category: Tetrahydrofurans, belongs to Tetrahydrofurans compound, is a common compound. In a patnet, author is Prakash, Rini, once mentioned the new application about 97-99-4.
Chemistry of bimetallic hexaborane(10) analogues: A combined experimental and theoretical study
Cluster nido-[3,6-{(OC)(3)Mn}(2)(B4H8 center dot THF)], 1, (THF = tetrahydrofuran), has been synthesized from the irradiation of [Mn-2(CO)(10)] with [BH3 center dot THF] at 255 nm along with R(OC)(4)Mn}(eta(6)-B2H6){Mn(CO)(3)}(2)(mu-H)], 2. Cluster 1 represents the new structural analogue of nido-homobimetallahexaborane(10) where the metal centers are arranged symmetrically in the non-adjacent basal positions of a pentagonal pyramid core. Theoretical calculation suggests that nido-1 is thermodynamically more stable as compared to the other hypothetical possible isomer nido-[4,5-{(OC)(3)Mn}(2)(B4H8 center dot THF)], II. Further, the reactivity of another homobimetallahexborane(10), nido[1,2-(Cp*Ru)(2)(mu-H)B4H9], 3 has been explored with borane that led to cluster build-up reaction to yield bimetallaoctaborane(12) analogues, nido-I(Cp*Ru)(2)B6H10(OH)(2)], 4 and nido-I(Cp*Ru)(2)B6H11(OH)], 5. All the clusters have been characterized by multinuclear NMR and IR spectroscopies as well as by mass spectrometric analysis. The structural types of 1 and 4 were unequivocally established by crystallographic analysis.
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Reference:
Tetrahydrofuran – Wikipedia,
,Tetrahydrofuran | (CH2)3CH2O – PubChem