The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 104-67-6, Name is Undecanoic gamma-Lactone, SMILES is O=C1OC(CCCCCCC)CC1, in an article , author is Cai, Xinpei, once mentioned of 104-67-6, Formula: C11H20O2.
Catalytic Hydroxycyclopropanol Ring-Opening Carbonylative Lactonization to Fused Bicyclic Lactones
A novel palladium-catalyzed ring opening carbonylative lactonization of readily available hydroxycyclopropanols was developed to efficiently synthesize tetrahydrofuran (THF) or tetrahydropyran (THP)-fused bicyclic gamma-lactones, two privileged scaffolds often found in natural products. The reaction features mild reaction conditions, good functional group tolerability, and scalability. Its application was demonstrated in a short total synthesis of (+/-)-paeonilide. The fused bicyclic gamma-lactone products can be easily diversified to other medicinally important scaffolds, which further broadens the application of this new carbonylation method.
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Reference:
Tetrahydrofuran – Wikipedia,
,Tetrahydrofuran | (CH2)3CH2O – PubChem