Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 5061-21-2, Name is 2-Bromo-4-butanolide, molecular formula is C4H5BrO2. In an article, author is Ma, Xiaoqin,once mentioned of 5061-21-2, Formula: C4H5BrO2.
Effect of different molecular architectured POSS-fluoropolymers on their self-assembled hydrophobic coatings
A total of 1/2/4/6-armed molecular architectured polyhedral oligomeric silsesquioxane (POSS) fluoropolymers were synthesized via atom transfer radical polymerization (ATRP) by linear (L), dicephalus (D), four-arm (T), and six-arm (S) initiators initiating same content of methyl methacrylate (MMA), methacrylate POSS (MA-POSS), and dodecafluoroheptyl methacrylate (DFHM). The obtainedL/D/T/S-(PMMA-b-PMAPOSS-b-PDFHM)(1/2/4/6) had increased molecular weight with arm increase. Driven by the stereo-hindrance and curvature effects of segments in tetrahydrofuran (THF), they assembled into the decreased spherical core-shell micelles (250-100 nm) with arm increase as PMA-POSS/PDFHM core and PMMA shell. Because of easy surface migration of fluorine-containing groups in small micelles, the casted film byS-(PMMA-b-PMAPOSS-b-PDFHM)(6) performed the fluorine-rich (46.44%) and rough (5.41 nm) surface, and therefore with the hydrophobic (112 degrees) and low water adsorption surface (1522 ng/cm(2)). Also, POSS-fluoropolymers obtained the enhanced thermostability with arm increase. It is believed that this research will provide a bright view for design and application of POSS-fluoropolymers.
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Reference:
Tetrahydrofuran – Wikipedia,
,Tetrahydrofuran | (CH2)3CH2O – PubChem