Some scientific research about Tetrahydrofuran-3-carboxylic acid

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Visible Light-Induced Regioselective Decarboxylative Alkylation of the C(sp2)?H Bonds of Non-Aromatic Heterocycles

With sunlight or blue LEDs irradiation, regioselective decarboxylative alkylation of various non-aromatic heterocycles has been realized via C(sp3)-centered radical C(sp2)?C(sp3) bond formation under oxidant-free conditions at room temperature. This reaction readily incorporates various functional alkyl groups into heterocyclic compounds without observation of any alkyl radical rearrangement and represents a mild and general tool for the preparation of valuable alkyl group-functionalized heterocyclic compounds. (Figure presented.).

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Properties and Exciting Facts About 87392-07-2

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COMPOUNDS AND THEIR METHODS OF USE

The present invention is directed to, in part, fused heteroaryl compounds and compositions useful for preventing and/or treating a disease or condition relating to aberrant function of a voltage-gated, sodium ion channel, for example, abnormal late/persistent sodium current. Methods of treating a disease or condition relating to aberrant function of a sodium ion channel including Dravet syndrome or epilepsy are also provided herein.

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Awesome Chemistry Experiments For Gamma-heptalactone

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Reductive Coupling of Ketones or Aldehydes with Electron-deficient Alkenes Promoted by Samarium Di-iodide

Samarium di-iodide is an efficient reagent for the reductive coupling of ketones or aldehydes and electron-deficient alkenes, whereby gamma-lactones can be prepared in good yields from ethyl acrylate.

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Can You Really Do Chemisty Experiments About 637-64-9

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Synthesis of chloroesters by the cleavage of cyclic and acyclic ethers using La(NO3)3¡¤6H2O as a mild and efficient catalyst under solvent-free conditions

A mild and an efficient synthesis of chloroesters is described by the reaction of cyclic and acyclic ethers with acid chlorides in the presence of a catalytic amount of La(NO3)3¡¤6H2O under solvent-free conditions, affording the corresponding chloroesters in excellent yields. Copyright Taylor & Francis Group, LLC.

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Can You Really Do Chemisty Experiments About 4971-56-6

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Synthetic Route of 4971-56-6, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 4971-56-6, Furan-2,4(3H,5H)-dione, introducing its new discovery.

A Novel One-Step Synthesis of 4H-Furo<3,4-b>pyrans and a Transformation into a Difuro<3,4-b:3',4'-e>pyridine

A simple one-step synthesis of 2-amino-4-aryl-5-oxo-4H-furo<3,4-b>pyran-3-carbonitriles 7 is described.It involves reaction of 2,4(3H,5H)-furandione (beta-tetronic acid) (5) with arylmethylenemalononitriles 4 in basic medium.Some substituent effects are noted and the assignments of 13C-NMR spectra are discussed.Ring transformation of the furo<3,4-b>pyran 7a leads to the difuro<3,4-b:3',4'-e>pyridine 9.Key Words: Furo<3,4-b>pyrans / Difuro<3,4-b:3',4'-e>pyridine / beta-Tetronic acid / Malononitriles, arylmethylene-

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Tetrahydrofuran – Wikipedia,
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Awesome Chemistry Experiments For (S)-Tetrahydrofuran-2-carboxylic acid

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Novel compounds

The present invention relates to novel retinoid-related orphan receptor gamma (RORgamma) modulators and their use in the treatment of diseases mediated by RORgamma.

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A new application about Tetrahydrofuran-3-carboxylic acid

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Reference of 89364-31-8, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.89364-31-8, Name is Tetrahydrofuran-3-carboxylic acid, molecular formula is C5H8O3. In a Article£¬once mentioned of 89364-31-8

Lead optimization of purine based orally bioavailable Mps1 (TTK) inhibitors

Efforts to optimize biological activity, novelty, selectivity and oral bioavailability of Mps1 inhibitors, from a purine based lead MPI-0479605, are described in this Letter. Mps1 biochemical activity and cytotoxicity in HCT-116 cell line were improved. On-target activity confirmation via mechanism based G2/M escape assay was demonstrated. Physico-chemical and ADME properties were optimized to improve oral bioavailability in mouse.

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Tetrahydrofuran – Wikipedia,
Tetrahydrofuran | (CH2)3CH2O – PubChem

Awesome and Easy Science Experiments about Gamma-heptalactone

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Reference of 105-21-5, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 105-21-5, molcular formula is C7H12O2, introducing its new discovery.

A hydroxyl-functionalized homochiral porous organic cage for gas chromatographic separations

A hydroxyl-functionalized homochiral porous organic cage (POC) was synthesized and characterized by FTIR, NMR, thermogravimetric analysis (TGA), MALDI-TOF-MS, and elemental analysis. The synthesized homochiral POC was used as stationary phase to prepare a capillary gas chromatography (GC) column by a static coating method. The fabricated column shows excellent selectivity not only for the separation of positional isomers but also for the resolution of various racemates. Thirty-nine racemates have been resolved on the column, including alcohols, diols, halohydrocarbons, epoxides, esters, lactones, ketones, ethers, and organic acids. Compared to the commercial beta-DEX 120 column and previously reported chiral POCs (CC3-R, CC9, and CC10)-coated columns, there are 11, 10, 24, and 15 tested racemates that?cannot be resolved on beta-DEX 120 column, CC3-R column, CC9 column, and CC10 column, respectively. This reveals that the fabricated column has prominent complementarity or superior separation performance to these columns in enantioseparation. Besides, the fabricated column can achieve some enantioseparations which are not?possible using all previously reported chiral POC-based columns. Some positional isomers (xylenes, dichlorobenzenes, dibromobenzenes, nitrochlorobenzenes, and nitrobromobenzenes) were also?separated with high-resolution values. The column exhibits good repeatability, reproducibility, and stability. The relative standard deviation (RSD) values of retention times were 0.03?0.18%, 0.11?0.92%, and 2.1?6.6% for run-to-run (n = 5), day-to-day (n = 5), and column-to-column (n = 3), respectively. The experimental results demonstrate the great potential of POCs for practical application in GC. [Figure not available: see fulltext.].

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Tetrahydrofuran – Wikipedia,
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Discovery of 3-Methyldihydrofuran-2,5-dione

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Synthesis of novel unsaturated AE-bicyclic analogues of lycoctonine, inuline and methyllycaconitine: With olefinic J = 13.5 Hz, but still cis

We have synthesised unsaturated AE-bicyclic analogues of lycoctonine class norditerpenoid alkaloids by acetylide addition and regiochemically controlled reductions. Reduction of a substituted propargylic alcohol with hydrogen gas (poisoned Pd catalyst) gave an alkene with vicinal J = 13.5 Hz. This was shown to be of Z-geometry by unambiguously preparing the corresponding E-alkene (J = 15.4 Hz).

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Awesome Chemistry Experiments For 453-20-3

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Related Products of 453-20-3, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 453-20-3, Name is 3-Hydroxytetrahydrofuran, molecular formula is C4H8O2. In a Article£¬once mentioned of 453-20-3

Enhancement of cyclic ether formation from polyalcohol compounds in high temperature liquid water by high pressure carbon dioxide

Cyclic ethers were produced by a dehydration reaction of polyalcohol compounds in high temperature liquid water, which was accelerated by the presence of carbon dioxide dissolved in the water. 3-hydroxytetrahydrofuran was produced by the dehydration of 1,2,4-butanetriol. Both tetrahydrofurfuryl alcohol and 3-hydroxytetrahydropyran were produced by the dehydration of 1,2,5-pentanetriol. Five-membered cyclic ethers were formed faster than six-membered cyclic ethers and the formation rates of the cyclic ethers depended strongly on the structure of the polyalcohol compounds. The position of the hydroxyl groups is crucial for the efficient intramolecular dehydration.

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Tetrahydrofuran – Wikipedia,
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