105-21-5, Gamma-heptalactone is a Tetrahydrofurans compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
In a dry round bottom flask under argon atmosphere 5 g (27.9 mmol) of (3- aminopropyl)trimethoxysilane (AMMO) was stirred at 50 C. 0.28 ml of 1 M triethylaluminium solution in hexane was slowly added (0.279 mmol, 1 mol%). Afterwards 27.9 mmol of the mono-substituted lactone listed in Table 1 was added and vigorously stirred for 3 hours. (0070) A yellowish and viscous following product from Comparative Example 1 was obtained. (0071) (0072) 1H NMR (400 MHz, Chloroform-c/) d 6.55 (s, OH), 3.51 (s, 5H), 3.19 – 3.12 (m, 1 H), 2.32 – 2.26 (m, 1 H), 1.84 – 1.71 (m, 1 H), 1.65 – 1.49 (m, 2H), 1.37 (m, 2H), 0.86 (t, J = 7.0 Hz, 1 H), 0.63 – 0.55 (m, 1 H); 13C NMR (101 MHz, CDCIs) d = 173.95, 70.74, 50.46, 41.92, 39.78, 33.10, 32.81 , 22.62, 18.86, 14.03, 6.45; 29Si NMR (79 MHz, CDCIs) d = -42.22.
105-21-5, As the paragraph descriping shows that 105-21-5 is playing an increasingly important role.
Reference£º
Patent; HENKEL AG & CO. KGAA; DAMKE, Jan-Erik; KLEIN, Johann; BRISAR, Rok; MEJIA, Esteban; (16 pag.)WO2019/115321; (2019); A1;,
Tetrahydrofuran – Wikipedia
Tetrahydrofuran | (CH2)3CH2O – PubChem